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Marie Curie, who won the Nobel Prize for Physics in 1903 jointly with her husband Pierre for their work on studying radiation. The first woman to win a Nobel Prize outright was Baroness Bertha Sophie Felicita von Suttner (I'm only typing that once!) who won the Nobel Peace Prize in 1905.
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Marie Curie became the first woman to win a Nobel Prize in 1903 when she won the prize for Physics.
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