ANSWERS: 1
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Click on their username or avatar to go to their profile. At the top of the blue section on the left (their info box) is an "Add as Friend" (or similar) link. Click it. It will change to Request Pending. When they accept you, it will show "You are Friends" on their profile, and they will appear on your friends list. (If they deny you, it could be because you have never had any contact with them through questions, answers or comments, or they've checked your current list, and don't like what they see (are you not a nice person?), or various other reasons. You can ask again later, or they may ask you, later. (Don't take it personally. Since the Friends Q&A is from this list, they may feel they have plenty of friends at the moment. Others don't care and may not use that list as much. Just wait a while (at least a few days) and try again. ;-) )
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